Smith,March - March's Advanced Organic Chemistry 6th Ed.pdf

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Frontmatter
MARCH’S ADVANCED
ORGANIC CHEMISTRY
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MARCH’S ADVANCED
ORGANIC CHEMISTRY
REACTIONS, MECHANISMS,
AND STRUCTURE
SIXTH EDITION
Michael B. Smith
Professor of Chemistry
Jerry March
Professor of Chemistry
WILEY-INTERSCIENCE
A JOHN WILEY & SONS, INC., PUBLICATION
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Copyright # 2007 by John Wiley & Sons, Inc. All rights reserved
Published by John Wiley & Sons, Inc., Hoboken, New Jersey
Published simultaneously in Canada
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Library of Congress Cataloging-in-Publication Data is available.
Smith, Michael B., March, Jerry
March’s Advanced Organic Chemistry: Reactions, Mechanisms,
and Structure, Sixth Edition
ISBN 13: 978-0-471-72091-1
ISBN 10: 0-471-72091-7
Printed in the United States of America
10987654321
CONTENTS
PREFACE
v
BIOGRAPHICAL NOTE
xv
ABBREVIATIONS
xvii
PART 1
1
1. Localized Chemical Bonding
3
2. Delocalized Chemical Bonding
32
3. Bonding Weaker than Covalent
106
4. Stereochemistry
136
5. Carbocations, Carbanions, Free Radicals,
Carbenes, and Nitrenes
234
6. Mechanisms and Methods of Determining Them
296
7. Irradiation Processes in Organic Chemistry
328
8. Acids and Bases
356
9. Effects of Structure and Medium on Reactivity
395
PART 2
417
10. Aliphatic Substitution: Nucleophilic and Organometallic
425
11. Aromatic Substitution, Electrophilic
657
12. Aliphatic, Alkenyl, and Alkynyl Substitution,
Electrophilic and Organometallic
752
13. Aromatic Substitution, Nucleophilic and Organometallic
853
14. Substitution Reactions: Free Radicals
934
15. Addition to Carbon–Carbon Multiple Bonds
999
xiii
 

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